Bis[2-(pyridin-2-yl)ethanol-κ2 N,O]bis(thiocyanato-κN)nickel(II)
نویسندگان
چکیده
In the title complex, [Ni(NCS)(2)(C(7)H(9)NO)(2)], the Ni(II) atom is in a distorted octa-hedral coordination environment defined by two N atoms of the two thio-cyanate ions and by the N and O atoms of the two chelating 2-(pyridin-2-yl)ethanol ligands. The complex mol-ecule is located around a crystallographic inversion center. In the crystal, mol-ecules are connected into a two-dimensional polymeric structure parallel to (100) by O-H⋯S hydrogen bonds.
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catena-Poly[[bis(methanol-κO)bis(thiocyanato-κN)cobalt(II)]-μ-1,3-bis(pyridin-4-yl)propane-κ2 N,N′]
The asymmetric unit of the title compound, [Co(NCS)(2)(C(13)H(14)N(2))(CH(3)OH)(2)], consists of one cobalt(II) cation located on a center of inversion, one half of a 1,3-bis-(pyridin-4-yl)propane ligand located on a twofold rotation axis, as well as one thio-cyanate anion and one methanol mol-ecule in general positions. The cobalt(II) cation is coordinated by two terminal N-bonded thio-cyanate...
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